Notes
Slide Show
Outline
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Why Water?
  • Because without it,
  • beer is kinda sludgey.
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What’s coming up…
  • Beer
  • Physical Characteristics
  • Beer
  • Ions and Minerals
  • Beer
  • Beer Styles and Water Types
  • Beer
  • Adjusting your water
  • Beer
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Don’t Freak Out!!
  • EID Water
    • Primarily from snowmelt/surface water
    • Low in dissolved minerals and hardness
    • EID’s annual WQ report lists concentrations
    • Good starting point for brewing any beer style
  • Well Water
    • Derived from groundwater
    • Local geologic conditions determine ions
    • Obtain lab analysis for specific concentrations
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Perspective from 1783…
  • “The proper season for brewing is between October and March but reigning opinion is not reliable for the former is too warm and the latter too close to spring.  The water may in October still have the smell of the weeds that have grown in it.   Some waters likewise breed innumerable quantities of insects and this is said to cause a very strong fermentation.”  (Poole 1783, from The Craft Of House-Brewing, Clive LaPense)


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Physical Characteristics
--Temperature
  • Probably the single most important factor to making good beer
  • Important throughout the brewing process:
    • Strike
    • Mash
    • Sparge
    • Boil
    • Fermentation
    • Lagering
    • Serving!
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Physical Characteristics
--pH
  • Critical for mash efficiency
  • Mash is naturally acidic due to grain
  • Proper range is 5.1 – 5.5 (measured at mash temperature)
  • Can measure pH with test strips
  • Ions in water affect pH, primarily:
    • Calcium, Magnesium, Bicarbonate, Sulfate


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Chemical Composition
Major Ions and Minerals
  • Calcium (Ca): chalk, gypsum
  • Magnesium (Mg): epsom salt
  • Bicarbonate (HC03): chalk, baking soda
  • Sulphate (SO4 ): gypsum, epsom salt
  • Sodium (Na): baking soda, canning salt
  • Chloride (Cl): calcium chloride, canning salt
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Calcium (Ca+2)
  • Primary mineral of hardness
  • Decreases mash pH
  • Stimulates enzyme activity
  • Stabilizes the alpha amylase
  • Essential component of yeast cells
  • Brewing salts: Chalk, Gypsum
  • Brewing range:  50-150 ppm
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Magnesium (Mg+2)
  • Secondary mineral of hardness
  • Enzyme co-factor (in the mash)
  • Essential as a yeast nutrient (10-20ppm)
  • Excess interferes with calcium solubility
  • Excess gives sour-bitter taste
  • Brewing salt: Epsom salt
  • Brewing range:  10-30 ppm
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Bicarbonate (HCO3-1)
  • Increases mash pH
  • Can reduce conc. by aeration, boiling, dilution
  • Brewing salts:  Baking soda, Chalk
  • Brewing range: 0-50 (for pales); 50-150 (amber beers); 150-250 (dark beers)
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Sulphate (SO4-2)
  • Accentuates hop bitterness
  • Brings out crispness in bitterness
  • Contributes to permanent hardness
  • Causes diarrhea above 750 ppm
  • Brewing salts:  Gypsum, Epsom salt
  • Brewing range: 50-150 ppm (for normally bitter beers; 150-350 for very bitter)
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Sodium (Na+1)
  • Water softeners may increase levels of Na
  • Can “round-out” beer flavor
  • Accentuates malt sweetness
  • Keep either sodium or sulfates in the low range to avoid harsh bitterness
  • Brewing salts:  Baking soda, Table salt
  • Brewing range: 0-150 ppm
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Chloride (Cl-1)
  • Enhances fullness and flavor
  • Mediciney above 300 ppm
  • Brewing salts:  Baking soda, Table salt
  • Brewing range: 0-250 ppm
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Water chemistry by region
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Pilsen
  • Very low hardness and alkalinity
  • Mash pH perfect from just base grains
  • Low sulfate enables mellow hop bitterness
  • Famous for crisp, light lagers
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Pollock Pines (i.e. EID)
  • Low hardness and alkalinity
  • Low sulfate enables mellow hop bitterness
  • Known for meth labs and the mexican restaurant
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Munich
  • High alkalinity from carbonates
  • Moderate in other minerals
  • Dark malts acidify the mash for proper pH
  • Famous for dunkels, bocks, and oktoberfests
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Vienna
  • Similar to Dortmund but less carbonates
  • Use toasted malts to achieve proper mash pH
  • Known for origin of red-amber lagers
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Dortmund
  • Similar to Vienna but more carbonates
  • Less hop assertiveness than Pilsner, but more malt due to higher overall mineral concentration
  • Famous for Dortmunder Export pale lager
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Dublin
  • High bicarbonate concentration
  • Low sodium, chloride, and sulfate
  • Known for its stout
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London
  • Toasted and dark malts counter high carbonate
  • Chloride and high sodium smooth out flavors
  • Famous for cooper colored pales and dark porters
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Edinburgh
  • More bicarbonate and sulfate than London’s water
  • Allows for heavier malt body requiring less hops
  • Famous for strong scotch dark ales, mellow hops
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Burton-on-Trent
  • High calcium and sulfate compared to London’s water
  • Alkalinity and hardness balanced like Pilsen’s water
  • High sulfate + low sodium = assertive hop bitterness
  • Famous for pale ales
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Modify your brewing water
  • Determine your source water ions
    • municipal water quality report from EID
    • independent lab for well water
    • or, just start with deionized water
  • Pick a target water type (e.g. Burton-on-Trent)
  • Calculate necessary additives to achieve target
    • Gypsum:  Ca & SO4
    • Epsom salt:  Mg & SO4
    • Canning salt:  Na & Cl
    • Baking soda:  Na & HCO3
    • Calcium chloride:  Ca & Cl
    • Chalk:  Ca & CO3
  • Tools available include Promash, Palmer’s Residual Alkalinity nomagraph, and Pratt’s excel solver tool




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Summary
  • pH and temperature play important roles
  • Mineral content critical to mash efficiency
  • Minerals affect hops bitterness characteristics
  • Extract brewers…mash is already done, no benefit to modifying water unless doing so for bitterness reasons